Search results for "Noble metals"
showing 4 items of 4 documents
Heterogeneous catalytic degradation of phenolic substrates: catalysts activity
2009
This review article explored the catalytic degradation of phenol and some phenols derivates by means of advanced oxidation processes (AOPs). Among them, only the heterogeneous catalyzed processes based on catalytic wet peroxide oxidation. catalytic ozonation and catalytic wet oxidation were reviewed. Also selected recent examples about heterogeneous photocatalytic AOPs; will be presented. In details, the present review contains: (i) data concerning catalytic wet peroxide oxidation of phenolic compounds over metal-exchanged zeolites, hydrotalcites, metal-exchanged clays and resins. (ii) Use of cobalt-based catalysts, hydrotalcite-like compounds, active carbons in the catalytic ozonation proc…
Characterisation and radiolysis of modified lithium orthosilicate pebbles with noble metal impurities
2017
Modified lithium orthosilicate (Li4SiO4) pebbles with additions of titanium dioxide (TiO2) are suggested as an alternative tritium breeding ceramic for the European solid breeder test blanket module. The noble metals – platinum (Pt), gold (Au) and rhodium (Rh), can be introduced into the modified Li4SiO4 pebbles during the melt-based process, due to the corrosion of Pt-Rh and Pt-Au alloy crucible components. In this study, the surface microstructure, chemical and phase composition of the modified Li4SiO4 pebbles with different contents of the noble metals was analysed. The influence of the noble metals on the radiolysis was evaluated after irradiation with accelerated electrons (E = 5 MeV),…
On the Interaction of Carbon Nanowires with Noble Metals through a Study of Their Surface-Enhanced Raman Spectra
2008
This paper deals with the interaction of linear carbon chains (polyynes) with silver and gold surfaces in the form of nanometer-sized clusters. Surface-enhanced Raman signals have been detected rev...
A solar photothermo-catalytic combined process for the VOCs combustion and the subsequent CO2 valorization using noble metal-free catalysts
2023
We here investigated a solar photothermo-catalytic combined process where the toluene (as volatile organic compound model) was first oxidized to CO2 which was subsequently converted into solar fuels in a second reactor. For this aim two noble-metal free catalytic systems were used, namely MnOx-ZrO2, which gave the best results for the toluene removal, and brookite TiO2-CeO2 mixed oxides which were the most efficient in the subsequent CO2 conversion. This latter reaction was further improved by the addition of small amounts of copper-based materials on brookite-ceria, acting as co-catalysts. The key point for both the examined reactions was the synergism between the thermocatalytic and the p…